Electric:Fuel Cell Cost and Reliability
Published: November 25, 2010, 12:00 am
Updated: May 7, 2012, 6:23 pm
This article has been reviewed by the following Topic Editor:
Margaret Swisher
Fuel cells today require some very expensive components. [1] In particular, the electrode/catalyst and polymer electrolyte membrane are literally worth their weight in gold.
A catalyst is a substance that promotes a chemical reaction without itself being consumed. As such, it must remain chemically inert under the conditions necessary for the reaction. Nearly all electrode/catalysts for hydrogen fuel cells contain platinum, a chemically inert metal that costs over $35 per gram, substantially more than the price of gold. At present, a typical fuel cell vehicle (100 kilowatt = 134 horsepower) contains over $70,000 of platinum. [2] Much of the current research on fuel cells focuses on minimizing the platinum needed for efficient catalysis. For example, one approach uses nanotechnology to produce tiny particles of platinum alloy with higher reactivity. These developments may someday bring platinum costs for a vehicle to below $5000. Then again, large-scale deployment of hydrogen fuel cell vehicles would increase the demand for platinum and thereby increase its price on world markets. Polymer electrolyte membranes in hydrogen fuel cells are usually constructed from a special type of Teflon called Nafion that is selectively permeable to positive electrical charges. This material is expensive, adding roughly $1000 to the cost of a vehicle. It also breaks down at temperatures above 80°C. Other materials, such as porous polyethylene film and aromatic polysulfone copolymers, may lower membrane costs to somewhere around $10 and can operate at higher temperatures. [3] Higher temperatures allow for more efficient use of platinum in the electrodes. [4]
Vehicles must function dependably despite being subjected to constant vibration, rapid temperature changes ranging from cold starts to high running temperatures, frequent bombardment with dirt and water, and occasional neglect or incompetence. Hydrogen fuel cell vehicles may not be ready for such abuse. Their membranes must be thin to attain sufficient permeability to gases, but this increases their fragility. Their catalysts must have a high surface area to attain sufficient reactivity, but this makes them vulnerable to contamination by dirt or poisoning by carbon monoxide. The water and temperature management of hydrogen fuel cells is complex. The principal reaction in a cell generates not only electric current, but also water and heat. If a fuel cell floods with water, hydrogen will not reach the catalyst, and the reaction will stop. If a fuel cell has too little water or the water freezes or boils, the membrane will suffer damage and lose permeability, and the fuel cell will overheat. To sustain operation, a fuel cell must be maintained under environmental conditions that are just right.
This is an excerpt from the book Global Climate Change: Convergence of Disciplines by Dr. Arnold J. Bloom and taken from UCVerse of the University of California.
©2010 Sinauer Associates and UC Regents
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Citation
Arnold J Bloom (Lead Author);Margaret Swisher (Topic Editor) "Fuel Cell Cost and Reliability". In: Encyclopedia of Earth. Eds. Cutler J. Cleveland (Washington, D.C.: Environmental Information Coalition, National Council for Science and the Environment). [First published in the Encyclopedia of Earth November 25, 2010; Last revised Date May 7, 2012; Retrieved May 22, 2013 <http://www.eoearth.org/article/Fuel_Cell_Cost_and_Reliability?topic=60604>
The Author
Arnold J. Bloom became a botanist through a circuitous route. Upon receiving an undergraduate degree in Physics from Yale University, he spent several years developing computer models of the spread of air pollution over cities in the USA and Germany. He received a Ph.D. in Biological Sciences from Stanford University, where he also completed a two-semester course in Environmental Legislation at the Law School. He conducted postdoctoral research on the temperature responses of plants at the ... (Full Bio)

Fuel cells today require some very expensive components. [1] In particular, the electrode/catalyst and polymer electrolyte membrane are literally worth their weight in gold.
A catalyst is a substance that promotes a chemical reaction without itself being consumed. As such, it must remain chemically inert under the conditions necessary for the reaction. Nearly all electrode/catalysts for hydrogen fuel cells contain platinum, a chemically inert metal that costs over $35 per gram, substantially more than the price of gold. At present, a typical fuel cell vehicle (100 kilowatt = 134 horsepower) contains over $70,000 of platinum. [2] Much of the current research on fuel cells focuses on minimizing the platinum needed for efficient catalysis. For example, one approach uses nanotechnology to produce tiny particles of platinum alloy with higher reactivity. These developments may someday bring platinum costs for a vehicle to below $5000. Then again, large-scale deployment of hydrogen fuel cell vehicles would increase the demand for platinum and thereby increase its price on world markets. Polymer electrolyte membranes in hydrogen fuel cells are usually constructed from a special type of Teflon called Nafion that is selectively permeable to positive electrical charges. This material is expensive, adding roughly $1000 to the cost of a vehicle. It also breaks down at temperatures above 80°C. Other materials, such as porous polyethylene film and aromatic polysulfone copolymers, may lower membrane costs to somewhere around $10 and can operate at higher temperatures. [3] Higher temperatures allow for more efficient use of platinum in the electrodes. [4]
Vehicles must function dependably despite being subjected to constant vibration, rapid temperature changes ranging from cold starts to high running temperatures, frequent bombardment with dirt and water, and occasional neglect or incompetence. Hydrogen fuel cell vehicles may not be ready for such abuse. Their membranes must be thin to attain sufficient permeability to gases, but this increases their fragility. Their catalysts must have a high surface area to attain sufficient reactivity, but this makes them vulnerable to contamination by dirt or poisoning by carbon monoxide. The water and temperature management of hydrogen fuel cells is complex. The principal reaction in a cell generates not only electric current, but also water and heat. If a fuel cell floods with water, hydrogen will not reach the catalyst, and the reaction will stop. If a fuel cell has too little water or the water freezes or boils, the membrane will suffer damage and lose permeability, and the fuel cell will overheat. To sustain operation, a fuel cell must be maintained under environmental conditions that are just right.
This is an excerpt from the book Global Climate Change: Convergence of Disciplines by Dr. Arnold J. Bloom and taken from UCVerse of the University of California.
©2010 Sinauer Associates and UC Regents
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